Question –
What is the concentration of KMnO4 solution in mole/litre which gives an absorbance of 0.120 when measured in a 2.0 cm cell ?
Solution –
A = Ɛ C l
A = absorbance
Ɛ = molar extinction coefficient = 1.8 x 104 litre / mole cm
C= concentration of KMnO4 in mole/litre
l = 2.0 cm
A = 0.120
0.120 = 1.8 x 104 x C x 2
C= 0.120/ 1.8 x 104 x 2
C= 0.033 x 10-4 = 3.3 x 10-6 mole/litre